Hi Pat,
I would think the best time would be when you are most alert because your brain will already be in the Beta range of frequencies and it wouldn't be that much further to go to Gamma. If you are going to do a "gamma" session, make sure that you only go there briefly because a prolonged visit to gamma land could leave you feeling more edgy than enlightened. It's a fine line between anxiety and "super on" and it's a state that can only be held for short bursts ... kind of like a flash of inspiration.
M.
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